Comparison of capillary zone electrophoresis performance of powder-blasted and hydrogen fluoride-etched microchannels in glass

The applicability of glass chips with powder-blasted microchannels for electrophoretic separations was examined, and the performance was compared to microchannels etched with hydrogen fluoride (HF), using bicarbonate buffer and rhodamine B and fluorescein as model compounds. The measured electroosmotic mobilities in all chips were comparable, with values of ca. 7 x 10(-4) cm(2) V(-1)s(-1). The effect of electrical field strength and detection length on the separation efficiency was monitored. It was found that the main source of dispersion is of the Taylor-Aris type, which was discussed in relation to channel roughness differences. Although in powder-blasted channels with a separation length of 8.20 cm, 7-9 times lower plate numbers were obtained than in a HF-etched channel with similar dimensions, successful separation of five fluorescein isothiocyanate (FITC)-labeled amino acids was obtained on a powder-blasted chip within 80 s. Efficiencies of up to 360 000 plates/m were demonstrated on this chip, when a higher buffer concentration was used at a field strength of 664 V/cm. It can be concluded that powder-blasted microchannel chips, although they have a lower separation efficiency compared to HF-etched chips, perform well enough for many applications. Powder blasting can therefore be considered a low-cost and efficient alternative to HF etching, in particular because of the possibility to fabricate access holes through the glass with the same process.     

Maximal monotonicity, conjugation and the duality product

Recently, the authors studied the connection between each maximal monotone operator and a family of convex functions. Each member of this family characterizes the operator and satisfies two particular inequalities.

The aim of this paper is to establish the converse of the latter fact. Namely, that every convex function satisfying those two particular inequalities is associated to a unique maximal monotone operator.

     

Asymptotic behaviour of the stability parameter for a family of singular-limit Hill's equation

Under some nondegeneracy conditions we give asymptotic formulae for the stability parameter of a family of singular-limit Hill's equation which depends on three parameters. We use the blow-up techniques introduced in [R. Martínez, A. Samà, C. Simó, Analysis of the stability of a family of singular-limit linear periodic systems in R⁴. Applications, J. Differential Equations 226 (2006) 652-686]. The main contribution of this paper concerns the study of the nondegeneracy conditions. We give a geometrical interpretation of them, in terms of heteroclinic orbits for some related systems. In this way one can determine values of the parameters such that the nondegeneracy conditions are satisfied. As a motivation and application we consider the vertical stability of homographic solutions in the three-body problem.     

Fusel oil as precursor for aroma generation by biotransformation using lipase

The feasibility of using mixtures of C4 and C5 chain-length aliphatic alcohols from fusel oil as the bulk organic media for lipase-mediated synthesis of laurate esters was assessed. Reaction mixtures consisted of lauric acid, lipase, solvent (if added), and appropriate amount of fusel oil (previously dehydrated with inorganic salts and molecular sieves). The influence of the reaction conditions such as substrate concentrations and temperature were investigated. Increased molar ratio of acyl donor to acyl acceptor allowed the esterification to proceed with no need for solvent addition.     

An Integrated Plant Design and Scheduling Problem in the Food Industry

An integrated plant design and scheduling problem in the food industry is discussed, and a solution is proposed. This involves the use of two models. The first model is an integer programming model that deals with long-term decisions. The second model deals with decisions that have to be made instantly.     

Ueber die symbolische Darstellung der Grundsyzyganten einer binären Form sechster Ordnung und eine Erweiterung der Symbolik von Clebsch

Ohne Zusammenfassung